Acid–base transport model depicting the dynamic pH response of interfacial reactions

Acid–base transport is integral to many important interfacial reactions in various fields of chemistry, but its theoretical foundation is lacked. Herein, a common acid–base transport model is established owing to the success in deriving buffer transport equations. This model is applicable to most buffer systems by flexibly integrating the transport equations in terms of buffer components, and is verified through the model relationships of buffer transport limiting current by using hydrogen evolution reaction experiments. Based on model calculations, two diagram approaches are proposed to depict the dynamic pH response and aid buffer operation optimizations. The model and methods allow us to quantify the rate-limiting effect of acid–base transport on interfacial reactions and to precisely control the effect through medium regulations. Furthermore, the model has laid the foundation of dynamic pH effect on species transformation and process mechanism, which can be of wide interest in the chemistry encompassing interfacial reactions.     

具有自动装卸搬运机器人的制造单元建模与分析

针对具有自动装卸搬运机器人的制造单元，着重考虑其双重资源约束的特点，提出了该系统的有限缓冲开排队网的建模方法。根据工件的加工、装卸与搬运等工艺流程，定义该系统的排队网模型的各种状态，基于连续时间马尔可夫链，采用精确解法对该模型进行分析求解，获得系统一系列的稳态性能指标。为了验证排队网建模方法的有效性，建立其对应的仿真模型，分别采用排队网模型的数值计算与仿真模型的仿真统计2种方法求出系统的性能指标进行对比，并基于排队网模型对该制造单元的系统性能进行分析，为该类制造单元的资源配置优化和设施布局优化等问题提供重要的理论支撑。     

Exploring the biomechanics of walking and crowd “flow”

Crowd movement simulation models are generally based on aggregated speed and flow data collected more than 50 years ago. There appears to be no validated modelling capability to include the impact of recent and future changes in population demographics, resulting from an ageing population and increasing obesity rates. New analytical approaches and data gathering are required to successfully model crowd movement and safety for current and future generations. This study carried out (a) a review of the primary components of crowd movement, demographics and analytical techniques, (b) prototype experiments to investigate age-related aspects of space and potential points of contact and (c) a new predictive model for crowd flow analysis based on pedestrian biomechanics and anthropometric data. The model uses the physical space taken up by the biomechanical walking process and the spatial buffer between points of potential contact with other pedestrians to predict the speed of movement at different levels of congestion. The new analytical model was used to predict single file speeds (for people with different demographics in congested space), which compared well with published experimental data. The next steps for model development for wider “flows” and additional experiments to provide data sets for wider demographics are also proposed.     

两种多层穿梭车系统的性能比较分析

物流配送中心订单响应速度的加快,对订单拣选系统提出了更高的要求。多层穿梭车系统因其柔性强、效率高等特点,近年来得到了广泛应用。多层穿梭车系统具有两种形式--基于转载车和基于环形输送线,二者均可实现货物的快速拣选,但在系统吞吐量和订单完成周期方面存在差异,致使企业决策者难以进行系统选择。基于上述原因,本文比较两种多层穿梭车系统的性能差异。建立两个系统的开环排队网络模型,然后求解系统吞吐量、订单完成周期,通过仿真验证了排队论模型的准确性,通过试验对两种系统的性能进行对比分析。结果表明,系统吞吐量与层数、巷道数相关,层数越多,巷道数越少,转载车系统相对于环线系统优势越显著;订单完成周期与层数、订单到达率相关,层数越多,订单到达率越低,转载车系统相对于环线系统越具优势。     

超前预留缓冲区交替式相向采掘沿空送巷的应用研究

为了减少工作面推采产生的矿压对沿空送巷的影响,采用预留采掘头面之间的安全缓冲区和合理避开矿压应力区,预留缓冲区交替式相向采掘工艺,实现矿井沿空送巷高效安全生产。     

Extending SSD Lifespan with Comprehensive Non-Volatile Memory-Based Write Buffers

Journal of Computer Science and Technology - New non-volatile memory (NVM) technologies are expected to replace main memory DRAM (dynamic random access memory) in the near future. NAND flash...     

基于缓冲对刀策略的自动化铲板组件设计

针对目前化纤纺丝生产中对喷丝板进行自动化铲板的需求,首先,提出一种自动铲板方法并设计了具有串并联弹簧缓冲对刀结构的铲板组件;然后,通过规划铲刀组件的对刀运动参数,建立组件的动力学模型,确定缓冲弹簧的刚度系数;同时对铲刀组件的对刀运动进行Adams仿真,验证运动参数设计和串并联弹簧缓冲对刀结构设计的正确性;最后,搭建了自动化铲板实验平台,开展对刀阶段的接触力测量实验。研究结果表明,实际对刀时的受力趋势与仿真结果一致,铲板组件可有效清洁喷丝板面,且随着铲刀接触力的增大铲板效果越明显,该研究为进一步开展自动化铲板系统的设计提供了技术参考。     

A resilient buffer allocation scheme in active queue management: a stochastic cooperative game theoretic approach

During the last decade, a plentiful number of active queue management schemes have been proposed, but their main objectives are simply allocating the buffer resource to all flows evenly, or protecting responsive flows from being degraded by unresponsive flows. However, the sending rates of the responsive flows can be determined diversely, and not all unresponsive flows have aggressively high sending rates. Furthermore, it is rational to reserve a portion of the buffer resource for certain privileged traffic. Grounded by these evidences, in this paper, we present a resilient active queue management algorithm, named Prior‐Core‐based Buffer Allocation considering diverse congestion control algorithms, fair‐unresponsive flows, and some privileged traffic. Our approach is based on stochastic cooperative game theory, where the payoffs yielded by cooperation are described by random variables, and the core is defined only over the distribution of these random payoffs; the core in this situation is called the prior‐core. As a result, it is shown that our buffer allocation, yielded by the prior‐core, achieves completely fair allocation for those flows whose requirement does not exceed the fair‐share regardless of the responsiveness, whereas aggressive flows are restricted according to availability of the buffer; all these are verified through ns‐2 simulation experiments. Copyright © 2014 John Wiley & Sons, Ltd.     

增效过磷酸钙的增效机制及其对玉米生长的影响

利用猪毛、风化煤和腐植酸钠的水解液为增效剂制备了一种增效过磷酸钙,探讨了增效过磷酸钙的增效机制及其对玉米生长的影响。结果表明,蒸馏水浸提条件下,增效过磷酸钙能减缓水溶磷的释放,具备较高的pH值缓冲性。与普通过磷酸钙相比,增效过磷酸钙处理的玉米生物量平均增加了41.9%,吸磷量和吸钙量分别增加了61.7%和27.8%,根系活力增加了24.3%。该研究结果对过磷酸钙生产的技术改进具有指导意义。